(E)-N-(1H-Pyrrol-2-ylmethylidene)-2-{[(E)-(1H-pyrrol-2-ylmethylidene)amino]methyl}aniline

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(1H-Pyrrol-2-ylmethylidene)(3-{[(1H-pyrrol-2-ylmethylidene)amino]methyl}benzyl)amine

In the title compound, C(18)H(18)N(4), the dihedral angles between the pyrrole rings and the phenyl ring are 85.07 (8)° and 77.13 (9)°. Inter-molecular N-H⋯N hydrogen bonds contribute to the stabilization of the crystal packing.

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2-[(E)-(1H-Pyrrol-2-ylmethyl­idene)hydrazinyl]pyridine monohydrate

The title hydrate, C(10)H(10)N(4)·H(2)O, shows a small twist in the hydro-zone derivative, the dihedral angle between the pyridine and pyrrole rings being 11.08 (12)°. The pyridine and pyrrole N atoms lie to the same side of the mol-ecule being sustained in place by hydrogen-bonding inter-actions with the water mol-ecule. Further inter-molecular O-H⋯N and N-H⋯O hydrogen bonding leads to the for...

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N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]benzohydrazide

In the title compound, C(13)H(13)N(3)O, the phenyl and pyrrole rings are inclined at 47.45 (8)°. In the crystal, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds form R(2) (1)(6) ring motifs. Mol-ecules connected through these hydrogen bonds are arranged into polymeric chains extending along the c axis.

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(E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline

The title compound, C14H16N2, is a pyrrole-2-carbaldimine ligand that shows an E conformation at the imine double bond. The dihedral angle between the rings is 78.3 (1)°. In the crystal, pairs of mol-ecules form centrosymmetric dimers [graph-set descriptor is presumably R(2)2(10)] via N-H⋯N hydrogen bonds between the pyrrole N-H group and the imine N atom of a neighbouring mol-ecule.

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2,3-Dimethyl-N-[(E)-(1H-pyrrol-2-yl)methyl­idene]aniline

In the title compound, C(13)H(14)N(2), the dihedral angle between the aromatic rings is 69.73 (14)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(10) loops. A weak C-H⋯π inter-action also occurs.

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ژورنال

عنوان ژورنال: IUCrData

سال: 2017

ISSN: 2414-3146

DOI: 10.1107/s2414314617005405